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CRC REEF RESEARCH CENTRE TECHNICAL REPORT No. 23

Chemical And Physical Characteristics Of Ballast Water: Implications For Treatment Processes And Sampling Methods.

Darren Oemcke, James Cook University
J. (Hans) van Leeuwen, University of New England

FOREWORD

The Ports Corporation of Queensland has provided funding, operational support and an industry focus for this research into the very important question of how to minimise the spread of exotic organisms via ships' ballast water. The Corporation believes that it is necessary for ballast water treatment to be rigorously evaluated using the best techniques available, both to determine the treatments that are likely to be successful as well as those that are not. This work by Mr. Oemcke and Prof van Leeuwen at the Cooperative Research Centre for the Ecologically Sustainable Development of the Great Barrier Reef, based in Townsville, Queensland, is among the first research of its kind and has led to a synthesis of important data and the development of new ideas. It provides the shipping and ports industries with high quality, relevant data, which can be used as a basis for proceeding towards the treatment of ballast water in an environmentally responsible and economical manner. Particularly, this report provides insights into the design requirements for ballast water treatment plants and the practical difficulties associated with the exchange of ballast water at sea.

The Ports Corporation of Queensland is operationally focused and does not usually provide financial support for fundamental research but, in this case, takes the view that this strategic research is of substantial long-term benefit and should lead to the further practical development of ballast water treatment systems by other organisations. The Corporation encourages national and international maritime industries to take this work into consideration as they further address ways of reducing the adverse impacts that have occurred, and are still occurring, as a result of ballast water being discharged into ports throughout the world. The Corporation commends the CRC Reef Research Centre Ltd for also supporting this research.

Derek Andrews
Chief Executive Officer
Ports Corporation of Queensland

EXECUTIVE SUMMARY

The Ballast Water Treatment project at the CRC Reef Research Centre Ltd, funded by the Ports Corporation of Queensland, aims to test technologies or techniques which can be used to remove exotic organisms from ships' ballast water. Techniques currently being examined for their potential to disinfect ballast water are ozonation, ultraviolet irradiation (UV) and filtration. To develop treatment systems for ballast water, it is necessary to understand some of the chemical and physical characteristics of the water to be treated.

The aims of the ballast water sampling program were to:

  1. Determine the sizes of solids and organisms present in ballast water and analyse the effectiveness of filtration both as a pretreatment to disinfection and as a disinfectant.

  2. Determine if ballast water, as landed after a voyage, had any characteristics which would impact adversely on filtration, UV irradiation or ozonation.

  3. Investigate the potential for chemical and physical characterisation of ballast water as a tool to verify that ballast water exchange had been conducted effectively.

  4. To develop sampling methods for determining the chemical and physical characteristics of ballast water.

Ballast water samples were taken from a number of vessels entering North Queensland ports during 1995 and 1996. Water, sludge and sediment samples were analysed for a range of physical and chemical characteristics which will affect filtration, UV irradiation and ozonation, and which may be useful for determining if ballast exchange at sea had been conducted.

Filtration may be necessary to reduce suspended solids prior to ozonation or UV irradiation. Only pilot testing can determine if it is necessary or effective. Without flocculation, screens of 20 to 30 µm would probably be necessary. Filters can also be used as a disinfection treatment for some organisms. 50 µm screens could be used as a stand alone treatment to remove zooplankton from ballast water and 20 µm screens should remove dinoflagellate hypnocysts, which are an important species of concern in ballast water. Viruses, bacteria, and many amoebae, protozoans, diatoms and dinoflagellate algae will not be effected by 20 µm screening.

UV irradiation may be limited to shipboard treatment, as the iron levels in ballast discharges may cause iron precipitation on UV lamps if UV is used after vessels deballast. Shipboard UV treatment of ballast water during ballasting, before iron from the ballast tanks contaminates the ballast water, will be unaffected by iron introduced from the ballast tanks. Shorebased treatment plants, where ballast is treated at the end of a voyage, will require pre-oxidation and clarification prior to UV irradiation. Newer vessels and vessels with good corrosion protection, will not contain such high levels of iron. Ozone is unlikely to be appropriate for ship board treatment of ballast water, due both to the possibility of increased corrosion of ballast tanks and the difficulty of maintaining a disinfection residual in an area high in dissolved iron and areas of sludge and sediment which are high in organic material.

The results of the sampling indicate that at least 14% of vessels which reported ballast exchange at sea had either done so ineffectively or failed to do so. It is possible that up to 57% had exchanged ineffectively, based on a chemical characterisation process, which compares the composition of ballast water with what would be expected from oceanic water. Problems with this type of comparison is re-contamination of the oceanic water by unexchanged sediments and water remaining in ballast tanks, even after the exchange process, and the effect that the presence of iron in some ballast tanks may have on measurements. Additional research is needed to determine the effectiveness of characterisation as a way of monitoring the exchange process.

The method used to sample ballast water, and the sample location have a substantial effect on the measured characteristics of the water collected. Problems with sampling methods and ways to overcome them are described.

 


THIS PUBLICATION IS CITED AS:
Oemcke, Darren & van Leeuwen, J. (Hans) (1998)
Chemical and physical characteristics of Ballast Water: Implications for treatment processes and sampling methods.
Technical Report No. 23
Townsville; CRC Reef Research Centre Ltd, 44 pp.

ISBN 1 876054 87 5

A full copy of this report may be obtained from the author(s), and through the following libraries:

Agency libraries: Great Barrier Reef Marine Park Authority, Townsville; Australian Institute of Marine Science, Townsville; James Cook University, Townsville; Queensland Department of Primary Industries and Fisheries (Brisbane and regional offices); Queensland Department of Environment and Heritage (Brisbane and regional offices); CSIRO Division of Marine Research, Tasmania.
Public libraries: Queensland, New South Wales, Tasmania and South Australia State libraries; National Library, ACT.
Parliamentary libraries: Queensland, New South Wales and South Australia parliamentary libraries.

Download a complete copy of the report(Adobe Acrobat File - 2.63MB)